Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Shota Teramae; Akane Kito; Tomoteru Shingaki; Yu Hamaguchi; Yuuki Yano; Takamori Nakayama; Yuko Kobayashi; Nobuki Kato; Naoki Umezawa; Yosuke Hisamatsu; Tetsuo Nagano; Tsunehiko Higuchi

doi:10.1039/c9cc03041g

Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Shota Teramae, Akane Kito, Tomoteru Shingaki, Yu Hamaguchi, Yuuki Yano, Takamori Nakayama, Yuko Kobayashi, Nobuki Kato, Naoki Umezawa, Yosuke Hisamatsu, Tetsuo Nagano, Tsunehiko Higuchi

研究成果: Article › 査読

3 被引用数 (Scopus)

抄録

Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

本文言語	English
ページ（範囲）	8378-8381
ページ数	4
ジャーナル	Chemical Communications
巻	55
号	58
DOI	https://doi.org/10.1039/c9cc03041g
出版ステータス	Published - 2019
外部発表	はい

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

文献へのアクセス

10.1039/c9cc03041g

他のファイルとリンク

引用スタイル

@article{055096c63b28431988aca90d8e983475,

title = "Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst",

abstract = "Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.",

author = "Shota Teramae and Akane Kito and Tomoteru Shingaki and Yu Hamaguchi and Yuuki Yano and Takamori Nakayama and Yuko Kobayashi and Nobuki Kato and Naoki Umezawa and Yosuke Hisamatsu and Tetsuo Nagano and Tsunehiko Higuchi",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc03041g",

language = "English",

volume = "55",

pages = "8378--8381",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "58",

}

TY - JOUR

T1 - Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

AU - Teramae, Shota

AU - Kito, Akane

AU - Shingaki, Tomoteru

AU - Hamaguchi, Yu

AU - Yano, Yuuki

AU - Nakayama, Takamori

AU - Kobayashi, Yuko

AU - Kato, Nobuki

AU - Umezawa, Naoki

AU - Hisamatsu, Yosuke

AU - Nagano, Tetsuo

AU - Higuchi, Tsunehiko

PY - 2019

Y1 - 2019

N2 - Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

AB - Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

UR - http://www.scopus.com/inward/record.url?scp=85069190744&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85069190744&partnerID=8YFLogxK

U2 - 10.1039/c9cc03041g

DO - 10.1039/c9cc03041g

M3 - Article

C2 - 31233056

AN - SCOPUS:85069190744

SN - 1359-7345

VL - 55

SP - 8378

EP - 8381

JO - Chemical Communications

JF - Chemical Communications

IS - 58

ER -

Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

抄録

ASJC Scopus subject areas

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル