Nanocrystal fabrication of acrylic acid derivatives with a long-alkyl group and their solid-state polymerization

Hitoshi Abe, Shuji Okada, Tatsumi Kimura, Satoru Shimada, Hiro Matsuda, Akito Masuhara, Hitoshi Kasai, Hidetoshi Oikawa

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Nanocrystals of octadecyl acrylate 1, octadecyl methacrylate 2 and N-octadecylacrylamide 3 were prepared by the reprecipitation method as water dispersion for the first time. Their sizes were from 120nm to 350nm depending on the preparation conditions. Although polymerization of 1 through 3 in nanocrystals was essentially the same as that in bulk crystals, it is interesting that 1 showed smaller average molecular weight and dispersity index in nanocrystals compared with in the bulk crystals.

本文言語English
ページ(範囲)70/[434]-76/[440]
ジャーナルMolecular crystals and liquid crystals
492
DOI
出版ステータスPublished - 2008

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

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