One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H2O)]ClO4 and K2[Hg(CN)4] {saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}

Hitoshi Miyasaka; Naohide Matsumoto

doi:10.1246/cl.1997.427

One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H₂O)]ClO₄ and K₂[Hg(CN)₄] {saltmen^2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}

Hitoshi Miyasaka, Naohide Matsumoto

研究成果: Article › 査読

5 被引用数 (Scopus)

抄録

The reaction of Mn(III) Schiff base complex [Mn(saltmen)(H₂O)]ClO₄ and [Hg(CN)₄]^2- gave two distinct compounds with respect to the formula ratio of Mn/Hg and structures, one is a 1-D polymeric compound [{Mn(saltmen)(H₂O)}{Hg(CNb)₃}]_n and the other is a discrete trinuclear compound [{Mn(saltmen)(H₂O)}₂{Hg(CN)₄}]. These compounds were synthesized by making vary the ratio of mixing two building blocks.

本文言語	English
ページ（範囲）	427-428
ページ数	2
ジャーナル	Chemistry Letters
号	5
DOI	https://doi.org/10.1246/cl.1997.427
出版ステータス	Published - 1997 1月 1
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.1997.427

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「One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H₂O)]ClO₄ and K₂[Hg(CN)₄] {saltmen^2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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title = "One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H2O)]ClO4 and K2[Hg(CN)4] {saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}",

abstract = "The reaction of Mn(III) Schiff base complex [Mn(saltmen)(H2O)]ClO4 and [Hg(CN)4]2- gave two distinct compounds with respect to the formula ratio of Mn/Hg and structures, one is a 1-D polymeric compound [{Mn(saltmen)(H2O)}{Hg(CNb)3}]n and the other is a discrete trinuclear compound [{Mn(saltmen)(H2O)}2{Hg(CN)4}]. These compounds were synthesized by making vary the ratio of mixing two building blocks.",

author = "Hitoshi Miyasaka and Naohide Matsumoto",

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T1 - One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H2O)]ClO4 and K2[Hg(CN)4] {saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}

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AB - The reaction of Mn(III) Schiff base complex [Mn(saltmen)(H2O)]ClO4 and [Hg(CN)4]2- gave two distinct compounds with respect to the formula ratio of Mn/Hg and structures, one is a 1-D polymeric compound [{Mn(saltmen)(H2O)}{Hg(CNb)3}]n and the other is a discrete trinuclear compound [{Mn(saltmen)(H2O)}2{Hg(CN)4}]. These compounds were synthesized by making vary the ratio of mixing two building blocks.

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