One-Step conversion to a disubstituted cyclopentenone from 2-Deoxy-D-Glucose and application to synthesis of prostaglandin e1 methyl ester

Takaaki Kamishima, Toshiyuki Nonaka, Toshihiro Watanabe, Yoshitaka Koseki, Hitoshi Kasai

研究成果: ジャーナルへの寄稿学術論文査読

5 被引用数 (Scopus)

抄録

We have developed a facile one-step conversion of 2-deoxy-D-glucose to form a disubstituted cyclopentenone through catalyst-free hydrothermal reaction under mild conditions. The use of 2-deoxy-D-glucose in one-pot conversion is to provide the formation of a carbon five-membered ring instead of the common biomass-derived furans such as furfural, 5-HMF, etc. The cyclopentenone has a potential to be a building block for the preparation of chemical products. As one example, we successfully demonstrated the synthesis of prostaglandin E1 methyl ester.

本文言語英語
ページ(範囲)1691-1696
ページ数6
ジャーナルBulletin of the Chemical Society of Japan
91
12
DOI
出版ステータス出版済み - 2018

フィンガープリント

「One-Step conversion to a disubstituted cyclopentenone from 2-Deoxy-D-Glucose and application to synthesis of prostaglandin e1 methyl ester」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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