Palladium-catalyzed alkynylthiolation of alkynes with triisopropylsilylethynyl sulfide

Masayuki Iwasaki; Daishi Fujino; Tatsuya Wada; Azusa Kondoh; Hideki Yorimitsu; Koichiro Oshima

doi:10.1002/asia.201100643

Palladium-catalyzed alkynylthiolation of alkynes with triisopropylsilylethynyl sulfide

Masayuki Iwasaki, Daishi Fujino, Tatsuya Wada, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

研究成果: Article › 査読

19 被引用数 (Scopus)

抄録

Regio- and stereoselective addition of a silyl-substituted alkynyl sulfide to various terminal alkynes proceeds in the presence of a palladium catalyst to give (Z)-1-thio-1,3-enynes, which are useful building blocks for the synthesis of polysubstituted 1,3-enynes. Addition to internal alkynes also takes place under solvent-free conditions (see scheme).

本文言語	English
ページ（範囲）	3190-3194
ページ数	5
ジャーナル	Chemistry - An Asian Journal
巻	6
号	12
DOI	https://doi.org/10.1002/asia.201100643
出版ステータス	Published - 2011 12月 2
外部発表	はい

ASJC Scopus subject areas

生化学
有機化学

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10.1002/asia.201100643

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abstract = "Regio- and stereoselective addition of a silyl-substituted alkynyl sulfide to various terminal alkynes proceeds in the presence of a palladium catalyst to give (Z)-1-thio-1,3-enynes, which are useful building blocks for the synthesis of polysubstituted 1,3-enynes. Addition to internal alkynes also takes place under solvent-free conditions (see scheme).",

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author = "Masayuki Iwasaki and Daishi Fujino and Tatsuya Wada and Azusa Kondoh and Hideki Yorimitsu and Koichiro Oshima",

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T1 - Palladium-catalyzed alkynylthiolation of alkynes with triisopropylsilylethynyl sulfide

AU - Iwasaki, Masayuki

AU - Fujino, Daishi

AU - Wada, Tatsuya

AU - Kondoh, Azusa

AU - Yorimitsu, Hideki

AU - Oshima, Koichiro

PY - 2011/12/2

Y1 - 2011/12/2

N2 - Regio- and stereoselective addition of a silyl-substituted alkynyl sulfide to various terminal alkynes proceeds in the presence of a palladium catalyst to give (Z)-1-thio-1,3-enynes, which are useful building blocks for the synthesis of polysubstituted 1,3-enynes. Addition to internal alkynes also takes place under solvent-free conditions (see scheme).

AB - Regio- and stereoselective addition of a silyl-substituted alkynyl sulfide to various terminal alkynes proceeds in the presence of a palladium catalyst to give (Z)-1-thio-1,3-enynes, which are useful building blocks for the synthesis of polysubstituted 1,3-enynes. Addition to internal alkynes also takes place under solvent-free conditions (see scheme).

KW - addition

KW - alkynyl sulfide

KW - alkynylthiolation

KW - enyne

KW - palladium

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JF - Chemistry - An Asian Journal

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Palladium-catalyzed alkynylthiolation of alkynes with triisopropylsilylethynyl sulfide

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