Preparation and properties of some stable captodative diphosphenes carrying the N‐(9‐fluorenyl)‐N‐mesitylamino group as an electron‐donating new sterically protecting auxiliary

Masatoshi Abe; Kozo Toyota; Masaaki Yoshifuji

doi:10.1002/hc.520040504

Preparation and properties of some stable captodative diphosphenes carrying the N‐(9‐fluorenyl)‐N‐mesitylamino group as an electron‐donating new sterically protecting auxiliary

Masatoshi Abe, Kozo Toyota, Masaaki Yoshifuji

理学研究科・化学専攻

研究成果: Article › 査読

6 被引用数 (Scopus)

抄録

The N‐(9‐fluorenyl)‐N‐mesitylamino group was utilized as an electron‐donating new sterically protecting group and thus several captodative 1‐amino‐2‐aryldiphosphenes were prepared. The push‐pull substituent effect on the ‐PP‐ bond was demonstrated by ³¹P NMR, and the reactivities of the captodative diphosphenes were studied.

本文言語	English
ページ（範囲）	427-432
ページ数	6
ジャーナル	Heteroatom Chemistry
巻	4
号	5
DOI	https://doi.org/10.1002/hc.520040504
出版ステータス	Published - 1993 10月

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1002/hc.520040504

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引用スタイル

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