Preparation of Mg-Al layered double hydroxide doped with Fe²⁺ and its application to Cr(VI) removal

Mg-Al layered double hydroxide (Mg-Al LDH) doped with Fe²⁺ was prepared by dropwise addition of a mixed solution of MgCl₂, FeCl ₂, and AlCl₃ to NaOH solution at a constant pH. The Fe²⁺-doped LDH was found to be able to remove Cr(VI) from an aqueous solution through the anion exchange of Cr₂O72- with the intercalated Cl^-, the production of Cr(OH)₃, and the adsorption of Cr₂O72- on the surface of the produced FeO(OH). The excellent performance of this LDH for Cr(VI) removal is caused by both the anion exchange properties of Mg-Al LDH and the reducing activity of the Fe²⁺ doped into the Mg-Al LDH. This process can be considered to occur through Langmuir-type adsorption, and the maximum adsorption amount and equilibrium adsorption constant are 12.5 mmol g^-1 and 242.1, respectively.