Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO2

Keiichi Tomishige; Ippei Furikado; Takashi Yamagishi; Shin Ichi Ito; Kimio Kunimori

doi:10.1007/s10562-005-6497-3

Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO₂

Keiichi Tomishige, Ippei Furikado, Takashi Yamagishi, Shin Ichi Ito, Kimio Kunimori

工学研究科・応用化学専攻

University of Tsukuba

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

22 被引用数 (Scopus)

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It is found that the addition of Mo to Rh/SiO₂ (Mo-Rh/SiO ₂) promoted alcohol formation in hydroformylation of propylene and ethylene, at the same time it drastically enhanced the activity of hydroformylation and hydrogenation. It is suggested that H₂ adsorption sites, which are not inhibited by CO adsorption, are present on Mo-Rh/SiO₂. The sites can cause high H₂ activation, and it can be related to the additive effect of Mo in hydroformylation reactions.

本文言語	英語
ページ（範囲）	15-21
ページ数	7
ジャーナル	Catalysis Letters
巻	103
号	1-2
DOI	https://doi.org/10.1007/s10562-005-6497-3
出版ステータス	出版済み - 2005 9月

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title = "Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO2",

abstract = "It is found that the addition of Mo to Rh/SiO2 (Mo-Rh/SiO 2) promoted alcohol formation in hydroformylation of propylene and ethylene, at the same time it drastically enhanced the activity of hydroformylation and hydrogenation. It is suggested that H2 adsorption sites, which are not inhibited by CO adsorption, are present on Mo-Rh/SiO2. The sites can cause high H2 activation, and it can be related to the additive effect of Mo in hydroformylation reactions.",

keywords = "Alcohol, Ethylene, Hydroformylation, Molybdenum, Propylene, Rhodium",

author = "Keiichi Tomishige and Ippei Furikado and Takashi Yamagishi and Ito, {Shin Ichi} and Kimio Kunimori",

year = "2005",

month = sep,

doi = "10.1007/s10562-005-6497-3",

language = "English",

volume = "103",

pages = "15--21",

journal = "Catalysis Letters",

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TY - JOUR

T1 - Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO2

AU - Tomishige, Keiichi

AU - Furikado, Ippei

AU - Yamagishi, Takashi

AU - Ito, Shin Ichi

AU - Kunimori, Kimio

PY - 2005/9

Y1 - 2005/9

N2 - It is found that the addition of Mo to Rh/SiO2 (Mo-Rh/SiO 2) promoted alcohol formation in hydroformylation of propylene and ethylene, at the same time it drastically enhanced the activity of hydroformylation and hydrogenation. It is suggested that H2 adsorption sites, which are not inhibited by CO adsorption, are present on Mo-Rh/SiO2. The sites can cause high H2 activation, and it can be related to the additive effect of Mo in hydroformylation reactions.

AB - It is found that the addition of Mo to Rh/SiO2 (Mo-Rh/SiO 2) promoted alcohol formation in hydroformylation of propylene and ethylene, at the same time it drastically enhanced the activity of hydroformylation and hydrogenation. It is suggested that H2 adsorption sites, which are not inhibited by CO adsorption, are present on Mo-Rh/SiO2. The sites can cause high H2 activation, and it can be related to the additive effect of Mo in hydroformylation reactions.

KW - Alcohol

KW - Ethylene

KW - Hydroformylation

KW - Molybdenum

KW - Propylene

KW - Rhodium

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UR - http://www.scopus.com/inward/citedby.url?scp=23944502370&partnerID=8YFLogxK

U2 - 10.1007/s10562-005-6497-3

DO - 10.1007/s10562-005-6497-3

M3 - Article

AN - SCOPUS:23944502370

SN - 1011-372X

VL - 103

SP - 15

EP - 21

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO2

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Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO₂