Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

Shogo Fujiki; Takumi Takada; Shota Nagasawa; Hiroshi Okada; Yusuke Sasano; Eunsang Kwon; Yutaka Matsuo; Yoshiharu Iwabuchi

doi:10.1039/d2cc06301h

Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

Shogo Fujiki, Takumi Takada, Shota Nagasawa, Hiroshi Okada, Yusuke Sasano, Eunsang Kwon, Yutaka Matsuo, Yoshiharu Iwabuchi

研究成果: Article › 査読

抄録

A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li⁺@C₆₀) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li⁺@C₆₀ with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.

本文言語	English
ページ（範囲）	1237-1240
ページ数	4
ジャーナル	Chemical Communications
巻	59
号	9
DOI	https://doi.org/10.1039/d2cc06301h
出版ステータス	Published - 2023 1月 4

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/d2cc06301h

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abstract = "A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.",

author = "Shogo Fujiki and Takumi Takada and Shota Nagasawa and Hiroshi Okada and Yusuke Sasano and Eunsang Kwon and Yutaka Matsuo and Yoshiharu Iwabuchi",

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AU - Fujiki, Shogo

AU - Takada, Takumi

AU - Nagasawa, Shota

AU - Okada, Hiroshi

AU - Sasano, Yusuke

AU - Kwon, Eunsang

AU - Matsuo, Yutaka

AU - Iwabuchi, Yoshiharu

PY - 2023/1/4

Y1 - 2023/1/4

N2 - A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.

AB - A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.

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JO - Chemical Communications

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Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

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