Spatial correlation between chemical and topological defects in vitreous silica: UV-resonance Raman study

M. Saito, F. Damico, F. Bencivenga, R. Cucini, A. Gessini, E. Principi, C. Masciovecchio

研究成果: ジャーナルへの寄稿学術論文査読

6 被引用数 (Scopus)

抄録

A spatial correlation between chemical and topological defects in the tetrahedron network in vitreous silica produced by a fusion process of natural quartz crystals was found by synchrotron-based UV resonance Raman experiments. Furthermore, a quantitative correlation between these defects was obtained by comparing visible Raman and UV absorption spectra. These results indicate that in vitreous silica produced by the fusion process the topological defects disturb the surrounding tetrahedral silica network and induce further disorder regions with sub nanometric sizes.

本文言語英語
論文番号244505
ジャーナルJournal of Chemical Physics
140
24
DOI
出版ステータス出版済み - 2014 6月 28

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