Stereocontrolled synthesis of ABC tricycle of solanoeclepin a

Masaatsu Adachi; Mai Torii; Toshio Nishikawa

doi:10.1055/s-0034-1380399

Stereocontrolled synthesis of ABC tricycle of solanoeclepin a

Masaatsu Adachi, Mai Torii, Toshio Nishikawa

研究成果: Article › 査読

7 被引用数 (Scopus)

抄録

A tricyclic compound possessing oxabicyclo[2.2.1]heptane and seven-membered ring of solanoeclepin A, the most active hatching agent of potato cyst nematode, was synthesized from d-pantolactone. The synthesis features a tin-mediated 6-exo-trig radical cyclization followed by iodoetherification and ring-closing enyne metathesis.

本文言語	English
論文番号	658
ページ（範囲）	965-969
ページ数	5
ジャーナル	Synlett
巻	26
号	7
DOI	https://doi.org/10.1055/s-0034-1380399
出版ステータス	Published - 2015 4月 1
外部発表	はい

ASJC Scopus subject areas

有機化学

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10.1055/s-0034-1380399

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AU - Torii, Mai

AU - Nishikawa, Toshio

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N2 - A tricyclic compound possessing oxabicyclo[2.2.1]heptane and seven-membered ring of solanoeclepin A, the most active hatching agent of potato cyst nematode, was synthesized from d-pantolactone. The synthesis features a tin-mediated 6-exo-trig radical cyclization followed by iodoetherification and ring-closing enyne metathesis.

AB - A tricyclic compound possessing oxabicyclo[2.2.1]heptane and seven-membered ring of solanoeclepin A, the most active hatching agent of potato cyst nematode, was synthesized from d-pantolactone. The synthesis features a tin-mediated 6-exo-trig radical cyclization followed by iodoetherification and ring-closing enyne metathesis.

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KW - iodoetherification

KW - natural products

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Stereocontrolled synthesis of ABC tricycle of solanoeclepin a

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