Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal

Hirokazu Masai; Shinji Tsuji; Takumi Fujiwara; Yasuhiko Benino; Takayuki Komatsu

doi:10.1016/j.jnoncrysol.2007.03.005

Structure and non-linear optical properties of BaO-TiO₂-SiO₂ glass containing Ba₂TiSi₂O₈ crystal

Hirokazu Masai, Shinji Tsuji, Takumi Fujiwara, Yasuhiko Benino, Takayuki Komatsu

工学研究科・応用物理学専攻

研究成果: Article › 査読

53 被引用数 (Scopus)

抄録

The BaO-TiO₂-SiO₂ crystallized glass containing Ba₂TiSi₂O₈ crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba₂TiSi₂O₈ showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba₂TiSi₂O₈ showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO₂-50SiO₂ transparent surface crystallized glass with strong c-oriented Ba₂TiSi₂O₈ phase showed its second-order non-linear optical constant, d₃₃ = 6.1 pm/V.

本文言語	English
ページ（範囲）	2258-2262
ページ数	5
ジャーナル	Journal of Non-Crystalline Solids
巻	353
号	22-23
DOI	https://doi.org/10.1016/j.jnoncrysol.2007.03.005
出版ステータス	Published - 2007 7月 1

ASJC Scopus subject areas

電子材料、光学材料、および磁性材料
セラミックおよび複合材料
凝縮系物理学
材料化学

文献へのアクセス

10.1016/j.jnoncrysol.2007.03.005

他のファイルとリンク

引用スタイル

@article{8a77365e93a64ac196fbe06f42e35d4c,

title = "Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal",

abstract = "The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.",

keywords = "Glass ceramics, Non-linear optics",

author = "Hirokazu Masai and Shinji Tsuji and Takumi Fujiwara and Yasuhiko Benino and Takayuki Komatsu",

note = "Funding Information: This work was partially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sport and Culture, Japan, the SCOPE (Strategic Information and Communications R&D Promotion Program) project by the Ministry of Public Management, Home Affairs, Posts and Telecommunications, Japan, the research collaboration with Asahi Glass Co. LTD., and the 21st century Center of Excellence (COE) Program in Nagaoka University of Technology. The authors are grateful to Professor M. Takada, Nagaoka University of Technology, for use of a spectroscopic ellipsometer.",

year = "2007",

month = jul,

day = "1",

doi = "10.1016/j.jnoncrysol.2007.03.005",

language = "English",

volume = "353",

pages = "2258--2262",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier",

number = "22-23",

}

TY - JOUR

T1 - Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal

AU - Masai, Hirokazu

AU - Tsuji, Shinji

AU - Fujiwara, Takumi

AU - Benino, Yasuhiko

AU - Komatsu, Takayuki

N1 - Funding Information: This work was partially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sport and Culture, Japan, the SCOPE (Strategic Information and Communications R&D Promotion Program) project by the Ministry of Public Management, Home Affairs, Posts and Telecommunications, Japan, the research collaboration with Asahi Glass Co. LTD., and the 21st century Center of Excellence (COE) Program in Nagaoka University of Technology. The authors are grateful to Professor M. Takada, Nagaoka University of Technology, for use of a spectroscopic ellipsometer.

PY - 2007/7/1

Y1 - 2007/7/1

N2 - The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.

AB - The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.

KW - Glass ceramics

KW - Non-linear optics

UR - http://www.scopus.com/inward/record.url?scp=34248579193&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34248579193&partnerID=8YFLogxK

U2 - 10.1016/j.jnoncrysol.2007.03.005

DO - 10.1016/j.jnoncrysol.2007.03.005

M3 - Article

AN - SCOPUS:34248579193

SN - 0022-3093

VL - 353

SP - 2258

EP - 2262

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 22-23

ER -