Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) 2]- salt

Daisuke Sato; Tomoyuki Akutagawa; Sadamu Takeda; Shin Ichiro Noro; Takayoshi Nakamura

doi:10.1021/ic061831u

Supramolecular rotor: Adamantylammonium([18]crown-6) in [Ni(dmit) ₂]^- salt

Daisuke Sato, Tomoyuki Akutagawa, Sadamu Takeda, Shin Ichiro Noro, Takayoshi Nakamura

研究成果: Article › 査読

44 被引用数 (Scopus)

抄録

Adamantylammonium (ADNH₃⁺) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH₃ ⁺)([18]crown6), which was introduced into a [Ni(dmit) ₂]^- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)₂]^- layers in the crystal, in which the molecular rotation of (ADNH₃ ⁺)([18]-crown-6) was confirmed from the temperature-dependent solid-state ¹H NMR.

本文言語	English
ページ（範囲）	363-365
ページ数	3
ジャーナル	Inorganic chemistry
巻	46
号	2
DOI	https://doi.org/10.1021/ic061831u
出版ステータス	Published - 2007 1月 22
外部発表	はい

ASJC Scopus subject areas

物理化学および理論化学
無機化学

文献へのアクセス

10.1021/ic061831u

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引用スタイル

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