@article{ed26c50cf5e14caebfa8028b034ffb74,
title = "Switching of the redox centers of a tris-2-mercaptophenolato chromium(iii) metalloligand by a guest metal ion",
abstract = "This work reports that the redox-active metalloligand (ML) fac-[CrIII(mp)3]3− (mp: 2-mercaptophenolato) coordinates with a Co(iii) ion to afford the trianionic complex [CoIII{fac-CrIII(mp)3}2]3−. The free ML shows ligand-centered redox processes, whereas the guest-metal-bound trinuclear structure exhibited a guest-metal-centered Co(ii)/Co(iii) redox couple, demonstrating redox switching through guest-metal binding to the MLs.",
author = "Masanori Wakizaka and Takeshi Matsumoto and Chang, {Ho Chol}",
note = "Funding Information: We would like to acknowledge Prof. Masahiro Yamashita, Dr Shinya Takaishi, and Dr Hiroaki Iguchi (Tohoku University) for their support with crystallographic and magnetic measurements, as well as Prof. Youichi Ishii and Dr Shintaro Kodama (Chuo University) for their support with elemental analysis. This work was supported financially by JSPS KAKENHI grants JP16K13967, JP16H04123, 26620050, and JP21H01756. Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",
year = "2023",
month = jan,
day = "19",
doi = "10.1039/d2dt03502b",
language = "English",
volume = "52",
pages = "1538--1542",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "6",
}