抄録
Metal phthalocyanines containing an unsymmetrically substituted nitro group were synthesized from 4-nitrophthalonitrile and the corresponding anhydrous metal salts (Co(OAc)2, Zn(OAc)2) by the method of statistically mixed condensation reactions. The new type of metallobisphthalocyanine compounds connected by a N=N bridge was prepared from the reactions of respective nitro compounds with sodium hydroxide (NaOH) and activated zinc powder in a mixture of methanol (MeOH) and tetrahydrofuran (THF). The structures of these compounds were characterized by using 1H NMR, IR, elemental analyses, UV-vis and magnetic circular dichroism spectroscopies.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 1140-1144 |
| ページ数 | 5 |
| ジャーナル | Journal of Porphyrins and Phthalocyanines |
| 巻 | 10 |
| 号 | 9-10 |
| DOI | |
| 出版ステータス | Published - 2006 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 化学 (全般)