Synthesis of shape-controlled and organic-hybridized hafnium oxide nanoparticles under sub- and supercritical hydrothermal conditions

Ameneh Sahraneshin, Seiichi Takami, Daisuke Hojo, Kimitaka Minami, Toshihiko Arita, Tadafumi Adschiri

研究成果: ジャーナルへの寄稿学術論文査読

27 被引用数 (Scopus)

抄録

In this study, hafnium oxide nanoparticles with different sizes and morphologies were synthesized under sub- and supercritical hydrothermal conditions and with and without organic surface modifiers. Transmission electron microscopy images showed that various shapes such as trapezohedron, oval-like and irregular shaped particles with sizes from 8 to 20 nm were obtained depending on the reaction conditions. The synthesized particles had monoclinic crystal structures as evidenced by their X-ray diffraction patterns. Chemical bonding of organic surface modifiers and their density on the particle surfaces were evaluated by Fourier transform infrared spectroscopy and thermogravimetric analysis. Furthermore, the effects of sub- and supercritical water state as the reaction medium and the presence of organic surface modifiers with different functional groups on the size and morphology of the particles are discussed.

本文言語英語
ページ(範囲)190-196
ページ数7
ジャーナルJournal of Supercritical Fluids
62
DOI
出版ステータス出版済み - 2012 2月

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