抄録
The synthesis of strophasterols C, E, and F has been accomplished from a 14,15-secoergostane derivative via a 1,3-dipolar cycloaddition of a nitrile oxide intermediate to simultaneously install an isolated cyclopentane ring and a C23 oxygen functionality in a diastereoselective manner and a regio- and diastereoselective selenohydroxylation of an olefinic intermediate under thermodynamic conditions. This synthesis also enabled the stereochemical confirmation of strophasterol C.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 1311-1315 |
| ページ数 | 5 |
| ジャーナル | Organic letters |
| 巻 | 22 |
| 号 | 4 |
| DOI | |
| 出版ステータス | Published - 2020 2月 21 |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学