The emergent intramolecular hydrogen bonding effect on the electronic structures of organic electron acceptors

Takashi Takeda; Yasutaka Suzuki; Jun Kawamata; Shin Ichiro Noro; Takayoshi Nakamura; Tomoyuki Akutagawa

doi:10.1039/c7cp04402j

The emergent intramolecular hydrogen bonding effect on the electronic structures of organic electron acceptors

Takashi Takeda, Yasutaka Suzuki, Jun Kawamata, Shin Ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa

研究成果: Article › 査読

10 被引用数 (Scopus)

抄録

A new strategy for controlling the electron-accepting ability of an anthraquinone (AQ)-based π-molecular system is proposed to take advantage of intramolecular hydrogen bonding interactions. The electron-accepting properties of AQ are enhanced by the introduction of bulky arylsulfonamide groups into AQ derivatives due to the formation of effective intramolecular N-H⋯O hydrogen bonding interaction and stabilization of the anion radical state even in solution.

本文言語	English
ページ（範囲）	23905-23909
ページ数	5
ジャーナル	Physical Chemistry Chemical Physics
巻	19
号	35
DOI	https://doi.org/10.1039/c7cp04402j
出版ステータス	Published - 2017

ASJC Scopus subject areas

物理学および天文学（全般）
物理化学および理論化学

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10.1039/c7cp04402j

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abstract = "A new strategy for controlling the electron-accepting ability of an anthraquinone (AQ)-based π-molecular system is proposed to take advantage of intramolecular hydrogen bonding interactions. The electron-accepting properties of AQ are enhanced by the introduction of bulky arylsulfonamide groups into AQ derivatives due to the formation of effective intramolecular N-H⋯O hydrogen bonding interaction and stabilization of the anion radical state even in solution.",

author = "Takashi Takeda and Yasutaka Suzuki and Jun Kawamata and Noro, {Shin Ichiro} and Takayoshi Nakamura and Tomoyuki Akutagawa",

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AU - Nakamura, Takayoshi

AU - Akutagawa, Tomoyuki

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AB - A new strategy for controlling the electron-accepting ability of an anthraquinone (AQ)-based π-molecular system is proposed to take advantage of intramolecular hydrogen bonding interactions. The electron-accepting properties of AQ are enhanced by the introduction of bulky arylsulfonamide groups into AQ derivatives due to the formation of effective intramolecular N-H⋯O hydrogen bonding interaction and stabilization of the anion radical state even in solution.

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The emergent intramolecular hydrogen bonding effect on the electronic structures of organic electron acceptors

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