The role of lattice vibration in the terahertz region for proton conduction in 2D metal-organic frameworks

Tomoya Itakura, Hiroshi Matsui, Tomofumi Tada, Susumu Kitagawa, Aude Demessence, Satoshi Horike

研究成果: ジャーナルへの寄稿学術論文査読

8 被引用数 (Scopus)

抄録

We studied the relationship between proton conductivity and the terahertz-regime vibrations of two-dimensional MOFs. The results of spectroscopy studies clarified the essential role played by the collective motions in the terahertz region in 2D layers for efficient H+ conduction. Ab initio calculations suggested the collective motion to be predominantly determined by the valence electronic structure, depending on the identity of the metal ion.

本文言語英語
ページ(範囲)1538-1541
ページ数4
ジャーナルChemical Science
11
6
DOI
出版ステータス出版済み - 2020 2月 14

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