Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

Masaaki Okazaki; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.1998.69

Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

高度教養教育・学生支援機構（機構レベル所属のみ）

研究成果: Article › 査読

2 被引用数 (Scopus)

抄録

Thermolysis of L_nIr(C₂H₅)(H) [L_n = {η²-Me₂Si(CH₂)₂PPh ₂}-(PMe₃)₂] led to the clean formation of a 1:1 mixture of ethene complex L_nIr(C₂H₄) and dihydrido complex L_nIr(H)₂. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

本文言語	English
ページ（範囲）	69-70
ページ数	2
ジャーナル	Chemistry Letters
号	1
DOI	https://doi.org/10.1246/cl.1998.69
出版ステータス	Published - 1998

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.1998.69

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引用スタイル

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abstract = "Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.",

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year = "1998",

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journal = "Chemistry Letters",

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AU - Okazaki, Masaaki

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1998

Y1 - 1998

N2 - Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

AB - Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

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